拓宽AnMBR处理城市污水的适用性通过PDMS膜进行溶解甲烷捕获:温度和流体力学的影响。

ty10086 提交于 周三, 08/25/2021 - 15:53
文章英文标题
Widening the applicability of AnMBR for urban wastewater treatment through PDMS membranes for dissolved methane capture: Effect of temperature and hydrodynamics.
正文
AnMBR技术是实现未来能源高效、环境友好的城市污水( UWW )处理的很有前景的替代技术。然而,出水中大量溶解甲烷的流失代表了潜在的高环境影响,阻碍了该技术进行全面应用的可行性。利用脱气膜( DM )捕集AnMBR出水的溶解甲烷可以被认为是解决这一问题的一个有趣的选择,尽管还需要进一步的研究来评估这一新兴技术的适用性。本研究的目的是评估操作温度和流体力学对DMs捕获AnMBR出水溶解甲烷的影响。为了实现这一目标,将一种商用聚二甲基硅氧烷( PDMS ) DM与一种常温处理UWW的工业样机AnMBR (示范规模)耦合。评价了不同的操作温度:11、18、24和30℃,并对DM进行了22 ~ 190 Lh-1m-2的不同液膜比( QL:A )操作,以研究体系对甲烷渗透的阻力。当温度升高、QL:A降低时,甲烷回收率最大,在温度为30℃、QL:A为25 Lh-1m-2时,甲烷回收率( MRE )约为85 %。研究表明,高的QL:A比阻碍了DM纤维的微扰回收甲烷,因为这种影响在较低温度下加剧可能是由于较高的液体粘度所致。同时,污垢评价表明,DM单元在处理AnMBR出水时,短期内可能不会出现明显的膜污染。提出了根据操作温度和QL:A预测系统整体传质的串联阻力模型,表明甲烷捕集受液相控制,高达总传质阻力的80 ~ 90 %。本研究进行的能量和环境评价表明,PDMS DMs将增强AnMBR技术处理UWW的能量回收和环境可行性,尤其是在低温下运行时。当MRE达到最大时,AnMBR与DM组合可实现每m3处理水0.87 k Wh和0.216 kg CO2 - eq的净能源产量和温室气体净减排量。
文章内容(英文)
AnMBR technology is a promising alternative to achieve future energy-efficiency and environmental-friendly urban wastewater (UWW) treatment. However, the large amount of dissolved methane lost in the effluent represents a potential high environmental impact that hinder the feasibility of this technology for full-scale applications. The use of degassing membranes (DM) to capture the dissolved methane from AnMBR effluents can be considered as an interesting alternative to solve this problem although further research is required to assess the suitability of this emerging technology. The aim of this study was to assess the effect of operating temperature and hydrodynamics on the capture of dissolved methane from AnMBR effluents by DMs. To this aim, a commercial polydimethylsiloxane (PDMS) DM was coupled to an industrial prototype AnMBR (demonstration scale) treating UWW at ambient temperature. Different operating temperatures have been evaluated: 11, 18, 24 and 30 °C. Moreover, the DM was operated at different ratios of liquid flow rate to membrane area (QL:A) ranging from 22 to 190 Lh-1m-2 in order to study the resistance of the system to methane permeation. Methane recovery was maximized when temperature raised and QL:A was reduced, giving methane recovery efficiencies (MRE) of about 85% at a temperature of 30 °C and a QL:A of 25 Lh-1m-2. The study showed that high QL:A ratios hinder methane recovery by the perturbation of the DM fibers, being this effect intensified at lower temperatures probably due the higher liquid viscosities. Also, the performed fouling evaluation showed that not significant membrane fouling may be expected in the DM unit at the short-term when treating AnMBR effluents. A resistance-in-series model was proposed to predict the overall mass transfer of the system according to operating temperature and QL:A, showing that methane capture was controlled by the liquid phase, which represented up to 80-90% of total mass transfer resistance. The energy and environmental evaluation performed in this study revealed that PDMS DMs would enhance energy recovery and environmental feasibility of AnMBR technology for UWW treatment, especially when operating at low temperatures. When MRE was maximized, the combination of AnMBR with DM achieved net energy productions and net greenhouse gas reductions of up to 0.87 kWh and 0.216 kg CO2-eq per m3 of treated water.
来源出处
Journal|[J]Journal of Environmental ManagementVolume 287, 2021. PP 112344-112344
DOI
https://doi.org/10.1016/J.JENVMAN.2021.112344

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