自然启发PDMS cumulonimbus微能量采集云

ty10086 提交于 周三, 08/25/2021 - 16:25
文章英文标题
Nature-inspired PDMS cumulonimbus micro-energy-harvesting cloud
正文
本工作利用聚二甲基硅氧烷( PDMS )中的去离子水( DI )制备了Cumulonimbus云模拟的纳米能量生成薄膜,采用多种表征方法验证了水的含量以及与云包裹的聚合物薄膜的形貌结构的相似性,包括扫描电子显微镜和光学反射成像技术。通过ATR - IR光谱在3266和1634   cm - 1处发现吸光度峰,验证了聚合物中水分的包封率;以镀铜的聚对苯二甲酸乙二醇酯( PET )片材为接触电极,采用简单的三明治工艺制备了器件。在外加电场作用下器件的介电研究被用来说明器件中存在界面跳跃和取向极化。当水含量从4:1增加到1:1时,器件的电压和电流分别提高了218 %和562 %;当水含量进一步增加时,器件的电压和电流分别降低了26 %和36.5 %。聚合物与水的最佳浓度选择为1:1,电流和电压的下降可能是由于水分子的凝聚导致水与聚合物分子之间的接触位点减少。器件的电压和电流分别增加了171.1   V和29.16 n A,采用自动输入系统增加了1 ~ 5   N的作用力。该装置在各种机械输入下进行测试,产生的能量作为敲击传感器、家门铃系统和海底振动检测仪的传感器,作为手机充电和LED照明的二次电源。
文章内容(英文)
Here in this work, nanoenergy-generating films mimicked from cumulonimbus cloud were prepared using deionised water (DI) in polydimethylsiloxane (PDMS). Various characterisation methods have been adopted to verify the content of water as well as the resemblance of the morphological structure of the water-entrapped polymer films with clouds which include scanning electron microscopy and optical reflectance imaging techniques. The water content entrapment in the polymer is verified using the ATR-IR spectroscopy by finding absorbance peaks at 3266 and 1634 cm−1. Polyethylene terephthalate (PET) sheets with a copper coating (Cu-PET) were used as contact electrodes, and the device was fabricated by the simple sandwiching process. Dielectric studies of the device under an applied electric field were used to illustrate the presence of interfacial hopping as well as orientational polarisation in the device. The device fabricated shows an enhancement of 218% and 562% with an increase in water content from 4:1 to 1:1 and a decrease of 26% and 36.5% with a further increase in water for the generated voltage and current measured, respectively. The optimum concentration of polymer to water is selected as 1:1 and the decrease in current and voltage may be due to the condensation of water molecules leading to fewer contact sites between the water and polymer molecules. The devices showed an increment of voltage and current of 171.1 V and 29.16 nA, respectively, with an increase in the force of 1–5 N by using an automated input system. The device was tested under various mechanical inputs, and the generated energy used as sensors in the knock sensor, home doorbell system and seabed vibration detector and as a secondary powering source for charging mobile phones and lighting LED.
来源出处
Journal|[J]Applied NanoscienceVolume 11, Issue 1. 2021. PP 127-137
DOI
https://doi.org/10.1007/S13204-020-01556-Y

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备注说明:

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